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Entropy

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What is Entropy? Entropy is a scientific concept that is most commonly associated with a state of disorder, randomness, or uncertainty. First law of thermodynamics The first law of thermodynamics states that energy can neither be created nor destroyed, only altered in form. Second law of thermodynamics Kelvin & Planck statement "No (heat) engine whose working fluid undergoes a cycle can absorb heat from a single reservoir, deliver an equivalent amount of work, and deliver no other effect" Clausius statement "No machine whose working fluid undergoes a cycle can absorb heat from one system, reject heat to another system and produce no other effect" Both statements of the Second Law constrains  the First Law of Thermodynamics  by identifying that energy goes downhill. The Second Law is concerned with Entropy (S) which is produced by all processes and associated with the loss of ability to do work. The Second Law states that the entropy of the universe increases.

Chemistry series Part II (Mercury - A Torture Killer)

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  We all know the trends on cine industry, if a feel good movies or any particular genre done well on market then more feel good movies or particular genre movies will come until the trend goes off. Recent trending film genre is violent movies, villains will kill innocent people violently in different ways that's the old way of making this genre movies but now even way of film making changed - Hero started killing people's on villain gang, then the main villain violently and some times innocent people (don't know why).   Mercury is such a torture killer, it will not kill people instantly but people who exposing themselves to mercury poisoning on regular basis will die eventually but the suffering will be brutal. We are going to see such real life incident's. The most famous one is Dr Karen Wetterhahn's death Many peoples died due to mercury poisoning but professor Karen wetterhahn's death stuns research field because she was a chemist - her profession was inves

Chemistry series Part I (Mercury - The hero and The villain)

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Sometime we failed to understand the real face of the people until time reveals it or we have do some research. Mercury is the perfect example. Yes, once celebrated as Hero (medicinal and many industrial uses) but now it was prohibited in many industries (Villain) and also poses risk towards environmental emissions and health. On periodic table, it has the symbol of Hg and its atomic number is 80. It exists in several forms 1) Elemental mercury 2) Inorganic mercury component 3) Methylmercury and other organic component Elemental mercury Shiny, silvery-white metal and liquid at room temperature. Exposed elemental mercury can evaporate to became an invisible, odourless toxic vapour, if heated it is colourless, odourless gas at room temperature. Elemental mercury is an element that has not reacted with another substance. When mercury react with another substance, it becomes a compound such as inorganic mercury component or organic mercury component. It is used in older thermometers, fluor

Steam Turbine - Part III ( Turbine casing and its components)

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Casing  Based on high inlet pressure and temperature the casing construction shall be either single or double shell type. The double shell construction prevents the steam contact to the outer casing joint and it will be used in case of high inlet steam conditions. Single casing has all its stages in the one casing and all are connected to a common drive shaft. Steam expansion, controlled / uncontrolled extraction provision within casing. Double casing turbines have the exhaust steam circulating in the annular space between the casings as in case of high steam inlet condition and also the steam within the space will be taken into controlled / uncontrolled extraction for process / feedwater heating if required. Double shell casing Single shell casing The parts of the turbine that control the position of the rotating components in relation to the fixed components are supported and located precisely at shaft height, they move independently of each other. For smaller turbine, bearing housin

Steam Turbine - Part II (Compounding of steam turbine)

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Compounding of steam Turbine Compounding method in which energy from the steam is extracted in several stages rather than a single stage in a turbine. In all turbines, the rotating blade velocity is proportional to the steam velocity passing over the blade. If the steam is expanded only in a single stage from the boiler pressure to the exhaust pressure, its velocity must be extremely high. A  compounded steam turbine has multiple stages,  i.e., it has more than one set of nozzles and rotors, in series, keyed to the shaft or fixed to the casing, so that either the steam pressure or the jet velocity is absorbed by the turbine in several stages Compounding will be done mostly on Impulse type Turbine and for Reaction turbine the same is not required (except few cases of severe application, only pressure compounding can be done but it is different from the compounding arrangement discussed below)   Velocity Compounding   A velocity-compounded impulse stage consists of a row of fixed

Steam Turbine - Part I (Introduction & its major types)

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Steam turbine is a type of turbomachine which is an assembly of nozzles and blades. It converts a part of the energy of high temperature and high-pressure steam (Enthalpy of steam into Kinetic in nozzle) into mechanical energy (or shaft work). The operation of steam turbine completely depends on the dynamic action of the steam expanding in nozzles.  The steam turbines are used for the generation of electricity in steam power plants varying from 1 MW to 1500 MW capacity. These are also used for marine propulsion. The steam turbines operate at very high speed (up to about 40,000 rpm) and are able to give efficiency about 40% which is higher than the other power producing devices. Because of its ability to develop tremendous power within a comparatively small space, the steam turbine has superseded all other Prime Movers , except hydraulic turbines, for generating large amounts of electricity and for providing propulsive power for large, high-speed ships. Today, units capable of generati